Not really... with a decoction the idea is that you not only remove a portion of the mash and heat it right up, which liquifies the small-granule starches from the grains; but that you
also then add this portion back to the original mash. This second bit is key because the original mash still contains all the enzymes required to convert the new starch into fermentable sugars. These enzymes would be destroyed by heat at the temperatures required to release the small-granule starches - so it's this ability to do a 'backwards temperature step' that makes a decoction special
You could get the same effect by boiling the entire mash and then adding exogenous enzyme, but that feels a bit unsporting LoL