I set the combi-boiler hot water to 65 and fill a couple of pots. No issues so far.
You would not have much control over sparge pH with that arrangement. Sparge pH is the most critical factor in avoiding tannin extraction.Don't think that would work too well. Combies generally need a decent flow to turn the boiler on and then flow for a bit until it starts heating the water.
I was thinking of putting an instant water heater on the cold feed to the shed but it's a bit pricey for the sake of filling a pot 2 or 3 times in the kitchen sink.
Diary spray and electric instant heat would be ideal for a small flow.