In no way does Argon stratify, neither does CO2. There is too much activity in the gas and they will just mix.
I did mention this in a previous comment.
although I see what you mean and I'm not really looking that deep into it but I had thought about this too when I was considering buying the dispense gun for my beer/cider making and came to the below conclusion before going ahead pulling the trigger on it.
Biggest factor there with respect to the gases mixing is the air turbulence.
I'm aware there'd wouldn't be complete displacement and there would be mixing, my approach to the process would likely be to purge it slowly at a low pressure and have limited movement of the dispensing equipment so that the mixing was minimised due to limited air turbulence in the bottle. Anything beyond the interacting boundary of the two gases should be displaced.
How deep that turbulent interacting boundary is would be related to the flow coming out of the dispense gun. If I limit it as much as possible, I should limit the depth of this inaction boundary.
A slow laminar flow of inert gas or CO2 (product dependent) would most certainly be ideal but realistically not possible.
Limiting the turbulence that is created would be the best approach.
A large enough purge theoretically should displace enough of the air in the bottle that a large portion of the oxygen is removed and any remaining oxygen that is mixed into the argon would be about as concerning as that which is introduced when a racking cane is pushed through the CO2 layer in a demijohn.
I'm not really too worried about this and for the sake of the process, I'm happy enough to say that it's the displacement of the air out of the bottle.
However, beyond the above
I'm dont see a reason to go too deep into the rabbit hole regard the science surrounding the idea. (I use this phrase loosely)
I'd never achieve what I set out to do if I were to get so caught up in ensure a completely isolated anaerobic environment.
The closest I'm willing to go is to compare the idea of doing this with the existing process the majority of people carry out for making wine.
Anything beyond that would just be being pedantic.
The majority of people don't purge bottles and they are capable of producing great wine, others do things the same way and get oxidation.
The purge should be more than adequate to reduce my chances of this occuring and thats all I care about.
It was that thought process that ultimately.lead to me buying a dispense gun for my beer so I'm happy to let the same logic apply here.
I have spunded and closed transfer when making sparkling elderflower wine.
Sparkling elderflower wine sounds absolutely delicious!
If you don't mind me asking, how did you go about your process of spunding and closed transfer? This is true that there jzls not be a need for it with normal wine but I can't help but want to try it