Hi and welcome to the forum
I mostly make 10L batches using a 12L stockpot but very occasionally do 5L.
What are you doing with the grains? Is this a partial mash or a extract brew(so steeping the grains)? If partial;
First of all you need to determine your boil off rate. Put 5L of water in the pot and boil it for 30 mins. Then measure it again. Then double it for your hours boil. This is your boil off. So say you boiled the 5L for 30 mins and you ended up with 4.5L (so 500ml boiled off), you boil off would be 1L.
You only need to do this once for that pot no matter what the brewlength of your batch. As long as your using the same pot and heat source
Then you have your grain absorbtion. There are a few different rates but I find 1L for 1kg, works fine. So in your case grain absorbtion would be 700ml (700g/700ml)
Plus your brew length, so 5L
So to put it all together
Boil off (so 1L for my made up example) + grain absorbtion (900ml) + brewlength (5L) = 6.7L