I'm not really sure I follow why you want to use your hot water.
You said you normally buy bottled water, rather than boiling your tap water, this leads me to assume there is something wrong with your tap water, hence why you don't use it at the moment.
Using Hot water is surely only a hot version of your tap water, if your tap water is bad, then all you will have is hot bad tap water, the fact it is hot won't have killed off any nasties, assuming there were some there in the first place, as it won't be hot enough.
The only thing treating with a Campden Tablet does is remove Chlorine and Chloramines from the water, it won't remove any bacteria, but there shouldn't be any in your tap water anyway.