I'm one who only ever uses boiling water to `sterilise' everything. Including glassware like bottles and demijohns. The secret is to pour it in very slowly so the glass has time to warm up and expand. Add it too quickly and bottles will shatter. One advantage of boiling water over chemicals with plastic such as FVs is that it will sanitise scratches as the heat penetrates the scratch even if the water itself doesn't. Chemicals of course can only work if the water can penetrate into the scratch.