I don't think it really matters from a beer point of view. There are differences depending on what chemicals you use in your cleaning regime, but it's mainly aesthetic. There is also an argument that a small amount of copper in the wort is good for the yeast. But one thing to bear in mind with brass is lead content. Nowadays most brass fittings have a low lead content, but depending on their source the opposite may be true. But don't be put off brass as thousands of people use brass fittings in their brewery and make good beer.