I think
@matt76 is right. I've been coming across reasons for lack of extract in (historic) brown malt due to the starch being damaged by heat and unconvertable to sugars. Brown Malt (and Amber) was dropped in favour of Pale Malt when it was learnt Pale Malt created far more soluble and fermentable matter than Brown Malt. Brown Malt was created "on-the-cheap" which meant shortcuts and creating malt that would be a bit charred. And the charring and browning reduced the sugars that could be converted.
Nothing to do with enzymes. Brown Malt certainly would have reduced enzymes, but nothing that some extra time mashing wouldn't put right. And if the starch wasn't damaged badly and was converted to unfermentable soluble dextrins, then there wouldn't be a drop in total extract, just a drop in fermentable extract as
@matt76 was describing:
... I mash everything at 67degC. So why does a pale ale fermented at 20degC with BRY-97 for example give me 75% apparent attenuation, while an American Stout mashed at the same temp, and fermented at the same temp with the same yeast give me only 63% AA? ...
It would be handy if the brewing calculators (like "Brewers Friend ", "Beersmith", etc) didn't include this unfermentable (and insoluble) material in their gravity calculations, but they do provide lots of confusing twaddle about
"PPG" and
"diastatic power" instead! (A reminder that I'm answering the OP too).
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I've been desperately trying to use the "diastatic power" figures in my emulations of historical malts but it's just been nowhere near accurate enough to provide anything more than a
guide. Commercial brewers might have "DP" figures for every batch of malt they receive, and that might be useful? We home-brewers are only just getting to grips with variable Alpha-Acid values for hops - we're decades away from being able to handle "diastatic power".
So; you have a mash with a calculated "DP" of only 30 or 40, does that mean your mash wont convert? No, certainly not! It means mashing has to be a bit more careful and for longer. But if you can't handle that, you aren't alone - the majority of home-brewers seemed to have an understanding of brewing processes being either on or off.
Done griping, and I haven't started on "PPG" which can at least be a little more useful once converted from the ridiculously arcane units ("points per pound per gallon" indeed! Even the "gallon" is an unrecognisable alien size in this case).