To wade in and give my two penneth - a 32A final ring circuit can comfortably deliver a full 32A providing it's been commissioned correctly. The breaker is there to protect the cable, so if there's any suggestion the circuit isn't rated for that load, the breaker should be de-rated.
In the UK we obsess about "ring mains" but the truth is they are a decades-old concept and are, in this day and age, pointless and potentially dangerous, especially after DIYers have got their hands on them. Some houses have them, some will have radials delivered using 4mm instead but, to the end user it's largely irrelevant; if the breaker is 32A and it's been installed by a competent individual then that's the load the circuit can take.
If a ring main is provided using 2.5mm solid-core T&E then, providing its integrity is intact, the capacity of the circuit (at a minimum, assuming the cable is buried rather than clipped directly) is roughly 40A so a 32A breaker is appropriate. This is why a final ring circuit can be potentially dangerous - because if the the ring has been broken (potentially unknowingly), it would essentially constitute two radial circuits, each with a current carrying capacity of 20A, but on a 32A breaker. This could be bad.
All of that said, I would, in my circumstance, personally have no worries about plugging in two 2kW devices into a quality double socket on a 32A final ring or radial circuit providing I was confident the electrics in the building wren't a complete shower
Edited to clarify : this is not provided as advice, it is provided as information of the regulations which is correct to the best of my knowledge and also on what I would personally be comfortable with in my setting, which is a known quantity. Others would be advised to have their installations regularly inspected professionally to ensure it is safe and compliant as a matter of course.